(Adds background, details) MONTREAL, Dec 2 (Reuters) - Canada's official opposition Liberals on Saturday unexpectedly chose former Environment Minister Stephane Dion as their new leader despite political shortcomings that could hinder his chances in an election expected next year. Dion, in fourth place after the first round of voting, beat former Harvard academic Michael Ignatieff on the fourth and final ballot at a Montreal leadership convention. Dion won by 2,521 votes to 2,084. The Liberals have dominated Canadian politics for the past century but lost power to the Conservatives in a January election. The Conservatives have a minority government that looks set to fall in 2007, sparking a new election. Dion won in part by stressing the need to do more for the environment, a topic of increasing importance to Canadians. But he has two potential strikes against him. First, he speaks English with a heavy French accent, which could make it hard to win over voters in what is a predominantly Anglophone country. Second, he is unpopular in his home province of Quebec, which accounts for a quarter of the seats in the federal Parliament. French-speaking separatists strongly dislike him for his efforts to prevent them from holding a successful referendum on whether Quebec should break away from the rest of Canada. An Ipsos-Reid opinion poll published on Friday said if Dion won the leadership, the Liberals would win 27 percent support if an election were held now, compared with 35 percent for the Conservatives.